{"id":5284,"productCode":"SPHF5D6T003N5","chemicalCode":"Hf","name":"Hafnium metal","customName":null,"otherNames":"","formula":"Hf","purity":99.95,"form":"SP","size":"5 inch dia x 0.25 inch th.","composition":"(Zr<0.75%)","description":"","productionMethod":"vac. melted","bulkAvailable":null,"productionStatus":"BO","hazmat":null,"status":null,"repackage":false,"priceBase":"","quantityBase":"pcs","bulkAvailability":true,"inProduction":"","factoryCode":"","publicComments":"machined with step","privateComments":"","chemicalCodeLetters":null,"image":null,"sizeData":"{\"formSize\":\"45\",\"size_form\":[{\"input_value\":\"5\"},{\"select\":{\"value\":\"inch\",\"options\":[{\"value\":\"mm\",\"text\":\"mm\"},{\"value\":\"inch\",\"text\":\"inch\"}]}},{\"text\":\"dia x\"},{\"input_value\":\"0.25\"},{\"select\":{\"value\":\"inch\",\"options\":[{\"value\":\"mm\",\"text\":\"mm\"},{\"value\":\"inch\",\"text\":\"inch\"}]}},{\"text\":\"th.\"}]}","isLocked":false,"isSearchable":false,"storedLocation":null,"chemicalId":523,"old_chem_id":null,"createdAt":"2020-08-04T19:44:46.000Z","updatedAt":"2026-08-03T17:44:15.043Z","deleted":false,"deletedAt":null,"userChangedById":18,"hts":null,"Chemical":{"id":523,"formula":"Hf","productLetters":"HF","name":"Hafnium ","otherNames":"Hafnium metal","cas":"7440-58-6","einecs":"231-166-4","hazmat":"Powder: Class 4.2, UN2545, PG II","data":"","applications":[{"title":"Sputtering","description":"Hafnium sputtering targets are used to deposit thin films for high-k dielectric layers and protective coatings in microelectronic devices."},{"title":"Semiconductors","description":"Hafnium is utilized in the fabrication of high-k gate dielectrics, such as hafnium dioxide, to reduce leakage current in advanced integrated circuits."},{"title":"Alloying","description":"Hafnium is added to nickel-based superalloys to improve grain boundary strength and oxidation resistance in high-temperature aerospace components."},{"title":"Evaporation materials","description":"High-purity hafnium pellets and wire are used as evaporation sources for the deposition of optical and protective thin films."},{"title":"Refractory chemicals","description":"Due to its high melting point and corrosion resistance, hafnium is used in specialized refractory applications and nuclear control rods."}],"publicComments":"<p style=\"text-align:justify;\"><span class=\"text-small\" style=\"color:#4d4d4d;\">High-purity hafnium metal is used in nuclear technology, where it serves as a control material due to its strong ability to absorb neutrons.</span><a href=\"#1\"><span class=\"text-tiny\" style=\"color:#999999;\"><sup>1</sup></span></a><span class=\"text-small\" style=\"color:#4d4d4d;\"> In aerospace and other extreme temperature applications, hafnium is added to refractory metal and superalloy systems to improve stability under harsh operating conditions.</span><a href=\"#1\"><span class=\"text-tiny\" style=\"color:#999999;\"><sup>2</sup></span></a><span class=\"text-small\" style=\"color:#4d4d4d;\"> Hafnium is used in optical coating and semiconductor fabrication, where it serves as a metal source for deposited layers and as a precursor for hafnium oxide and related compound films formed during deposition.</span><a href=\"#1\"><span class=\"text-tiny\" style=\"color:#999999;\"><sup>3,4</sup></span></a><span class=\"text-small\" style=\"color:#4d4d4d;\"> This material is commonly supplied in forms suitable for evaporation and physical vapor deposition processes used in thin-film and coating production.</span><a href=\"#1\"><span class=\"text-tiny\" style=\"color:#999999;\"><sup>4</sup></span></a></p>","privateComments":"Hafnium is a transition metal used in filaments, electrodes, semiconductors, gate insulators, neutron absorption in control rods, and nuclear power plants. It has mechanical properties and corrosion-resistance that make it useful in alloys, pressurized water reactors, military reactors, and naval reactors. Due to its heat resistance and affinity to oxygen and nitrogen it is used as a scavenger for oxygen and nitrogen in glass-filled and incandescent lamps. Radioactive isotopes of hafnium have a large half-life and are used to trace the evolution of Earth’s mantle.","specialNotes":"","specialNotesProduct":false,"sds":"public/sds/Hf.pdf","smiles":"","inchi":"","inchiKey":"","molecularWeight":"","iupac":"","eccn":"","hts":"","atomicNumber":72,"atomicWeight":"178.49 u","meltingPoint":"2233 °C","boilingPoint":"4603 °C","density":"13.31 g/cm³","crystalStructure":"Hexagonal close-packed","colorAppearance":"Steel gray","thermalConductivity":"23.0 W/(m·K)","electricalResistivity":"33.1 μΩ·cm","coefficientOfExpansion":"5.9 µm/(m·K)","electronegativity":"1.3","neutronCrossSection":"104 barns","electronConfiguration":"[Xe] 4f14 5d2 6s2","createdAt":"2023-05-08T18:30:57.000Z","updatedAt":"2026-04-28T21:07:44.924Z","deleted":false,"deletedAt":null,"userChangedById":19,"customContent":"","displayFormula":"","bottomText":"<p id=\"1\"><span class=\"text-tiny\" style=\"color:#999999;\">References:</span></p><p style=\"font-family:Calibri;font-size:10.0pt;margin:0in;\"><span style=\"color:#999999;\"><strong>1. International Atomic Energy Agency (IAEA) </strong><i>Advances Control Assembly Materials for Water Reactors.&nbsp;</i>IAEA-TECDOC-813.</span></p><p style=\"font-family:Calibri;font-size:10.0pt;margin:0in;\"><span style=\"color:#999999;\">2. <strong>Lütjering, G.; Williams, J. C. </strong><i>Titanium</i>, 2nd ed., Springer, 2007.</span></p><p style=\"font-family:Calibri;font-size:10.0pt;margin:0in;\"><span style=\"color:#999999;\">3. Ohring, M., <i>Materials Science of Thin Films</i>, 2nd ed., Academic Press, 2002.</span></p><p style=\"font-family:Calibri;font-size:10.0pt;margin:0in;\"><span style=\"color:#999999;\">4. <strong>Mattox, D. M. </strong><i>Handbook of Physical Vapor Deposition (PVD) Processing</i>, 2nd ed., Elsevier, 2010.</span></p>","isAiData":true,"isHazmatAsPowder":false,"hazmatAsPowder":"","tags":[{"id":17,"name":"Infrared Optical Materials","link":"optics_ir_chemical","type":"chemical"},{"id":58,"name":"Semiconductor","link":"semiconductor_chemical","type":"chemical"},{"id":308,"name":"3D Printing","link":"3d_printing_chemical","type":"chemical"},{"id":419,"name":"Refractory Metals and Compounds","link":"refractory_chemicals","type":"chemical"},{"id":420,"name":"Evaporation Deposition Materials ","link":"evaporationdepositionmaterials_chemicals","type":"chemical"},{"id":421,"name":"Optical Coating Materials","link":"opticalcoatingmaterials_chemicals","type":"chemical"}]},"userChangedBy":{"email":"vmykhnenko@ltschem.com","username":"vmykhnenko","name":"Veronika Mykhnenko"},"ProductPrice":[{"id":125422,"productId":5284,"price":5236,"quantity":1,"um":"pc","locked":false,"isShow":false,"createdAt":"2020-08-18T17:28:21.000Z","updatedAt":"2020-08-18T17:28:21.000Z","bulkAvailable":null,"bulkAvailability":false,"packaging":null,"customerId":null,"type":"default","version":1,"quoteId":null}],"Vendor":[],"tags":[{"id":5,"link":"sputtering_product","name":"Sputtering","description":"","text":null,"image":null,"icon":null,"type":"product","toShowOnMainPage":false,"showImageAndDescription":true,"createdAt":"2024-08-12T22:58:50.192Z","updatedAt":"2025-03-21T19:08:28.627Z","deletedAt":"2025-03-21T19:08:28.627Z","userChangedById":null}],"favorites":[],"attachments":[]}